While I have seen Skyfall and thought it was very good, I need more time and need to rewatch it before putting it in the list. (probably be 4 or 5 though)

1. Goldfinger
2. Casino Royale
3. Goldeneye
4. From Russia with Love
5. On Her Majesty's Secret Service
6. The Spy Who Loved Me
7. Thunderball
8. Dr. No
9. You Only Live Twice
10. The Man with The Golden Gun
11. Live and Let Die
12. For Your Eyes Only
13. Die Another Day
14. The World is Not Enought
15. Diamonds are Forever
16. Moonraker
17. Tomorrow Never Dies
18. License to Kill
19. The Living Daylights
20. Quantum of Solace
21. Octopussy
22. A View to a Kill